Fact
Sheets: MSDS: How To Read A Material Safety Data Sheet
TWU members who work around
chemicals frequently ask, "What is this stuff and what
is it doing to me?" Most public employees are now
covered by Right-to-Know laws which require employers to
supply workers with information on the identity of the
chemicals they are exposed to, their health effects and
training on how to handle them safely. In addition, all
containers of hazardous materials must carry a warning
label.
The details of these laws may differ from state to
state, but they all require employees to have access to
a Material Safety Data Sheet (MSDS) which contains
information on health hazards, chemical ingredients,
physical characteristics, control measures, and special
handling procedures for all hazardous substances in the
work area. The laws say that MSDSs must be readily
accessible to all employees. It is also illegal to have
any blanks on the sheet. If no information exists, "no
information " must be written in the space.
Because federal law requires all chemical manufactures
and distributors to produce and distribute MSDSs, public
employees who are not covered by a Right-to-Know law may
still be able to obtain an MSDS from their employer or
directly from the chemical manufacture or distributor.
The laws state that MSDSs must contain complete,
accurate, and up-to-date information. Nevertheless, many
MSDSs are inaccurate and incomplete. They may, however,
still be very useful if you know how to read them and
where to look for more information. Many states have
agencies that will check the accuracy of MSDSs and the
TWU Safety Department can also assist.
MSDSs may differ slightly in organization, but they must
all contain the same basic information on hazardous
ingredients, health effects, legal and recommended
exposure limits, physical properties, and control
methods.
Section I -- Material Identification
The name of the product and name, address, and
emergency telephone number of the manufacturer must be
provided.
Section II -- Hazardous Ingredients/Identity
Information
Which Chemicals are Covered?
State laws differ about which chemicals are required
to be listed on an MSDS. Those states with laws similar
to the Federal OSHA hazard communication standard
require evaluation of all chemicals. All those found to
be hazardous are covered by the law. Some states,
however, require coverage of only the chemicals which
have OSHA standards (about 500 chemicals). Other laws
contain a list of thousands of chemicals that must be
included, while a few require all ingredients to be
listed, even those which are not hazardous. Assume that
all of the chemicals that you work with should be
included unless the manufacturer or employer can prove
otherwise.
The percentage concentration of each substance in a
mixture may also be listed, but this is not required by
most state laws. This is unfortunate, because it is
useful to know what the other, "non-toxic" chemicals in
the mixture are.
What are the Names of the Chemicals?
Chemicals are often known by different names:
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A trade name,
such as "Safety Clean", is the brand name the
manufacturer gives the product. It does not tell
you, however, what chemicals are in the product, or
whether the product is a mixture of chemicals or a
single chemical. The same chemical may be used in a
variety of products with different trade names. The
trade name usually appears on the label and in
Section I of the MSDS.
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A generic name
describes a family or group of chemicals. For
example, there are several different "isocyanates",
and thousands of different "chlorinated
hydrocarbons". Sometimes an MSDS will try to get
away with just listing the generic names. However,
the law says that chemical names must also be
listed.
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The chemical or
specific name is the one that describes -the
specific chemical. An example is methyl chloroform,
one of the thousands of "chlorinated hydrocarbons",
or toluene disocyanate, a member of the "isocyanate"
family. The chemical name is the easiest name to use
when doing research on the health effects of
chemicals and how to protect yourself.
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The-CAS Number
is a number given by the Chemical Abstract Service
to each chemical. While different chemicals may have
the same name, they will all have their own CAS
number which can be used to look up information. The
Chemical Abstract Service publishes a book that
contains a list of all CAS Numbers and the chemicals
they represent.
The
MSDS must list the chemical name of all hazardous
ingredients which make up more than 1% of the mixture
(or 0.1% for cancer-causing substances). Listing only
the trade name, only the CAS number or only the generic
name is not acceptable.
Trade Secrets
The manufacturer may be able to withhold ingredient
information from the MSDS if any ingredients are trade
secrets. Procedures for challenging a manufacturer's
trade secret claim are determined by different state
laws. Under most Right-to-Know laws, the manufacturer
must provide the trade secret identities to health care
professionals and/or workers if they have a need to know
the information, or in a medical emergency. Consult your
state law for more details. Remember that even if
certain ingredients in the product are labeled as trade
secrets, the MSDS must contain all of the other required
information.
Exposure Limits
The MSDS must also list the OSHA Permissible
Exposure Limit (PEL) for each hazardous ingredient. It
must also list Threshold Limit Values (TLVS) recommended
by the American Conference of Governmental Industrial
Hygienists and may also list workplace exposure limits
recommended by the National Institute for Occupational
Safety and Health (NIOSH). These are important because
ACGIH and NIOSH often recommend exposure limits that are
more up-to-date and protective than OSHA's.
Section III -- Physical/Chemical Characteristics
Physical and chemical characteristics include the
chemical's appearance and odor, along with physical
properties that indicate how easily a chemical will
evaporate and release potentially harmful vapors into
the air.
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Boiling point:
The boiling point
of a substance is the temperature at which the
liquid boils or becomes a gas. The lower the boiling
point, the quicker it evaporates and the easier it
is to inhale. Chemicals with boiling points below
100 C (or 212 F) require special caution.
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Vapor pressure:
A high vapor pressure indicates that a liquid will
evaporate easily. Chemicals which evaporate quickly
are called volatile. This means that air
concentrations can build up quickly, even though the
substance is in liquid form. Liquids with high vapor
pressures may be especially hazardous if you are
working with them in a confined space or an enclosed
area.
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Vapor density:
If the vapor density is less than one, it will tend
to rise in air. If the vapor density is greater than
one, it will fall in air and concentrate in the
bottom of tanks or confined spaces.
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Appearance and odor:
This
information may help identify a substance that
spills or leaks in your work area. However, many
chemicals are hazardous at levels lower than they
can be smelled. Also, many chemicals, such as
hydrogen sulfide and ammonia, cause "olfactory
fatigue", which means that workers rapidly lose
their ability to smell the substance.
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Specific gravity:
If the
specific gravity is greater than one, the substance
will sink in water; if less than one, it will float
on top of water.
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Evaporation rate:
This is the
rate at which a substance evaporates compared to
either ether, which evaporates quickly, or butyl
acetate, which evaporates slowly. If the substance
has an evaporation rate greater than one, it
evaporates faster than the comparison substance.
Section IV -- Fire and Explosion Hazard Data
This section should provide information on the fire
hazards of a product and special precautions necessary
to extinguish a fire.
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Flash point:
This is the lowest
temperature at which a liquid gives off enough vapor
to form a mixture with air that can be ignited by a
spark. Liquids with flash points below 100 F are
considered flammable, and liquids with flash points
between 100 and 200 F are considered to be
combustible. Flammable and combustible liquids
require special handling and storage precautions.
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Extinguishing media:
This section should specify what kind of fire
extinguisher to use. There are four classifications
of fires: Class A for paper and wood, Class B for
more flammable materials such as liquids or greases,
Class C for electrical fires, and Class D for fires
involving metals or metal alloys.
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Special firefighting
procedures and unusual fire and explosion hazards:
For example,
some chemicals (such as corrosives) must not be
extinguished with water in case of fire.
Section V -- Reactivity Data
When stored
improperly, some chemicals can react with other
chemicals and release dangerous materials. This
describes the reaction of chemicals when they are mixed
together with other chemicals, or when stored or handled
improperly.
Section VI -- Health Hazard Data
This section describes the health effects of the
product, including signs and symptoms of exposure and
medical conditions made worse by exposure. Acute
(short-term) and chronic (long-term) effects of exposure
must always be included. MSDSs often leave out chronic
health information, such as whether a chemical causes
cancer or birth defects.
Routes of entry (inhalation, skin contact, swallowing)
and emergency and first aid procedures must also be
included. Unfortunately, a lot of MSDSs in circulation
do not contain complete and accurate health hazard
information.
This section must also contain information on target
organs (liver, kidneys or central nervous system), signs
or symptoms of exposure, medical conditions generally
aggravated by exposure, and emergency First Aid
procedures.
Section VII -- Precautions for Safe Handling and Use
(Spill or Leak Procedures)
This section contains information on proper
equipment to use and what precautions to follow if a
spill or leak occurs. It should also describe safe waste
disposal methods and precautions to be taken in handling
and storing.
Section Vlll -- Control Measures
The MSDS must list control measures that can reduce
or eliminate the hazard, including ventilation and other
engineering controls, safe work practices, and personal
protective equipment.
For respirators, information on the type of respirator,
degree of protection and the appropriate filter
cartridge (such as acid gases, dust or organic vapors)
must be included. In addition, all gloves do not protect
against all chemicals. The correct type of glove should
be specified on the MSDS.
CHECKING THE ACCURACY OF MSDSs
What can be done if you suspect that the MSDS that
you received is not accurate or complete?
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Ask your Employer:
If an MSDS is not accurate, your employer is
responsible for obtaining an accurate, complete MSDS.
Ask your employer to request a more accurate MSDS
from the supplier or manufacturer.
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Contact the
Manufacturer:
The union can contact
the manufacturer and ask for a more accurate MSDS.
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Call OSHA:
Your state OSHA (if
applicable) can check MSDSs and give you more
accurate information. Federal OSHA can also require
a manufacturer to redo an MSDS if the information is
inaccurate or incomplete.
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Call NIOSH:
The toll-free number
for information about chemical identities, health
effects or other information is (800) 356-4674.
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Contact your TWU Safety
Representative:
Your TWU safety
representative may have information on the chemicals
you use and also has access to the TWU International
Occupational Safety & Health Department which can
analyze MSDSs.
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